Laboratoire de Chimie Moléculaire et Thio-organique

Dr Jérôme BAUDOUX

Lecturer in Organic Chemistry

Section du Comité National n° 16
Section du CNU n° 32

Jérôme Baudoux obtained his PhD at the University of Rouen (2004) under the supervision of Dr. Jean-Christophe Plaquevent and Dr. Dominique Cahard. He studied the synthesis of ionic liquids with an axial chirality and a mesogenic behavior to develop asymmetric organocatalysis in new ionic liquid media. In 2004, he undertook postdoctoral position at the University of Nottingham with Professor Nigel S. Simpkins to develop rapid and efficient access to the tetracyclic model compounds and the synthesis of Welwitindolidinone alkaloid derivatives. In 2005, he worked in the group of Professor Pierre-Jean Madec in order to optimize new supported ionic liquid phase (SILP) catalysts using chitosan as support. Since 2006, he was appointed lecturer in organic chemistry at the University of Caen. His research currently focuses on organocatalysis, the development of new synthetic methodologies, the synthesis of functionalized organic salts (ionic liquids) for different applications.

Teaching

Teaching in organic synthesis (1^st to 4^thyear), Nitrogen chemistry (4^thyear), Organometallics (4^thyear), Chromatography (3^rdyear). ¹H NMR, IR, UV and mass spectrometry (3^rd and 4^th years).

Key publications

Sulfonates as Versatile Structural Counterions of Epoxidized Salts
Kui, T.; Chardin, C.; Rouden, J.; Livi, S.; Baudoux, J.
ChemSusChem, 2022, 1-6.
Doi : 10.1002/cssc.202200198

CNSL, a Promising Building Blocks for Sustainable Molecular Design of Surfactants: A Critical Review
Roy, A.; Fajardie, P.; Lepoittevin, B.; Baudoux, J.; Lapinte, V.; Caillol, S.; Briou, B.
Molecules, 2022, 27 (4), 1443.
Doi : 10.3390/molecules27041443

Sulfonimides versus ketosulfonamides as epoxidized imidazolium counterions: towards a new generation of ionic liquid monomers
Chardin, C.; Durand, A.; Jarsale, K.; Rouden, J.; Livi, S.; Baudoux, J.
New Journal of Chemistry, 2021, 45 (6), 2953-2957.
Doi: 10.1039/d0nj05126h

New Epoxy Thermosets Derived from a Bisimidazolium Ionic Liquid Monomer: An Experimental and Modeling Investigation
Radchenko, A. V.; Chabane, H.; Demir, B.; Searles, D. J.; Duchet-Rumeau, J.; Gerard, J.-F.; Baudoux, J.; Livi, S.
ACS Sustainable Chemistry & Engineering, 2020, 8 (32), 12208-12221.
Doi: 10.1021/acssuschemeng.0c03832

Cycloaliphatic epoxidized ionic liquids as new versatile monomers for the development of shape memory PIL networks by 3D printing
Radchenko, A. V.; Duchet-Rumeau, J.; Gerard, J.-F.; Baudoux, J.; Livi, S.
Polymer Chemistry, 2020, 11 (34), 5475-5483.
Doi: 10.1039/d0py00704h

Antibacterial surface based on new epoxy-amine networks from ionic liquid monomers
Livi, S.; Lins, L.; Capeletti, L.; Chardin, C.; Halawani, N.; Baudoux. J.; Cardoso, M. B.
European Polymer Journal, 2019, 116, 56-64.
Doi: 10.1016/j.eurpolymj.2019.04.008

Self-Catalyzed Coupling between Bronsted-Acidic Imidazolium Salts and Epoxy-Based Materials: A Theoretical/Experimental Study
Perchacz, M.; Matejka, L.; Konefal, R.; Seixas, L.; Livi, S.; Baudoux, J.; Benes, Hynek; Donato, Ricardo K.
ACS Sustainable Chemistry & Engineering, 2019, 7 (23), 19050-19061.
DOI: 10.1021/acssuschemeng.9b04810

Access to Anti or Syn 2-Amino-1,3-diol Scaffolds from a Common Decarboxylative Aldol Adduct
Chaumont, P.; Baudoux, J.; Maddaluno, J.; Rouden, J.; Harrison-Marchand A.
J. Org. Chem. 2018, 83 (15), 8081-8091
DOI: 10.1021/acs.joc.8b00901

DMDO as a valuable oxidant for the synthesis of polyfunctionnal aromatic imidazolium skeletons bearing epoxides
Chardin, C.; Rouden, J.; Livi, S.; Baudoux, J.
Green Chem. 2017, 19, 5054-5059.
DOI: 10.1039/C7GC02372C

Thioamide-subtituted cinchona alkaloid derivatives as efficient organocatalysts
Singjunla, Y.; Pigeaux, M.; Laporte, R.; Baudoux, J.; Rouden,J.
Eur. J. Org. Chem. 2017, 4319-4323.
DOI: 10.1002/ejoc.201700870

Straightforward and stereoselective synthesis of a,ß-diamino acid derivatives by an organocatalyzed decarboxylative Mannich reaction
Singjunla, Y.; Baudoux, J.; Rouden, J.
Eur. J. Org. Chem. 2017, 3240-3243.
DOI:10.1002/ejoc.201700468