Laboratoire de Chimie Moléculaire et Thio-organique

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Key factor affecting the basicity of mesoporous silicas MCM-41: effect of surfactant extraction time and Si/Al ratio
B. Boukoussa; Z. Kibou; Z.Abid; R. Ouargli; N. Choukchou-Braham; D.Villemin; A.Bengueddach; R.Hamacha
Chemical Papers, 2017 sous presse.
DOI: 10.1007/s11696-017-0279-4

Catalyst Free Diels-Alder reactions of vinylphosphonates with cyclopentadienones
Benmeddah A.; Villemin D.; Mostefa-Kara B.; Bar N.; Legay, R.
Can. J. Chem. 2017, 95: 871–879.
DOI: 10.1139/cjc-2017-0267

Synthesis, conductivity, and vibrational spectroscopy of tetraphenylphosphonium bis(trifluoromethanesulfonyl)imide.
Haddad, B.; Paolone, A.; Villemin, D.; Taqiyeddine, M.; Belarbi, E.-h.; Bresson, Serge;  Rahmouni, M.; Dhumal, N.; Kim, H.; Kiefer, J.
J. Mol. Struct. 2017, 1146, 203-212.
DOI: 10.1016/j.molstruc.2017.05.138.

Selective study of elimination of Cd (II) and Pb (II) from aqueous solution by novel hybrid material
Mohamed Kadari, Messaadi Mahassene, M’hamed Kaid, Mouffok Ben Ali, D. Villemin.
J. Chin. Adv. Mater. Soc., 2017, 3, 149-157
DOI: 10.1080/22243682.2017.1329027.

Synthesis, experimental and theoretical vibrational studies of 1-methyl and 1,2-dimethyl, 3-propyl imidazolium bis(trifluoromethanesulfonyl) imide
M Drai, A Mostefai, A Paolone, B Haddad, E Belarbi, D Villemin, S Bresson, O Abbas, Y Chaker, M Rahmouni,
J. Chem. Sci. 2017, 12, 6, 707-719

Studies on the feasibility of using a novel phosphonate resin for the separation of U(VI), La(III) and Pr(III) from aqueous solutions
H. Bendiaf, O.Abderrahim, D. Villemin, M. A.Didi,
J. Radioanal. Nucl. Chem., 2017, 312, 587-597.
DOI: 10.1007/s10967-017-5244-8.

Programmed site-selective palladium catalyzed arylations of thieno[3,2-b]thiophene
T. M. Ha Vuong, D. Villemin, H.-H. Nguyen, T. Thanh L, T. T. Dang, H. Nguyen,
Chemistry – An Asian Journal 2017, sous presse
DOI: 10.1002/asia.201700562.

Chemoinformatics and stereoisomerism: a stereo graph kernel together with three new extensions
P.-A. Grenier; L. Brun; D.Villemin
Pattern Recogn. Let., 2017, 87, 227-230.
DOI: 10.1016/j.patrec.2016.06.025

DMDO as a valuable oxidant for the synthesis of polyfunctionnal aromatic imidazolium skeletons bearing epoxides
Chardin, C.; Rouden, J.; Livi, S.; Baudoux, J.
Green Chem. 2017, (accepté le 14 septembre et publié online)
DOI: 10.1039/C7GC02372C

Metal free, borinic acid-catalyzed phosphine oxides, sulfoxides and N-oxides reductions
Chardon, A.; Rouden, J.; Blanchet,
J. ChemCatChem 2017, (accepté le 28 août et publié online)
DOI: 10.1002/cctc.201700986

Thioamide-subtituted cinchona alkaloid derivatives as efficient organocatalysts
Singjunla, Y.; Pigeaux, M.; Laporte, R.; Baudoux, J.; Rouden,J.
Eur. J. Org. Chem. 2017, 4319-4323.
DOI: 10.1002/ejoc.201700870

Straightforward and stereoselective synthesis of a,ß-diamino acid derivatives by an organocatalyzed decarboxylative Mannich reaction
Singjunla, Y.; Baudoux, J.; Rouden, J.
Eur. J. Org. Chem. 2017, 3240-3243.

Gaining Insight Into Reactivity Differences Between Malonic Acid Half Thioester (MAHT) and Malonic Acid Half Oxyesters (MAHO)
Bew, S. P.; Stephenson, G. R.; Rouden, J.; Godemert, J.; Seylani, H.; Martinez-Lozano, L. A.
Chem.-Eur. J. 2017, 23, 4557-4569.

Borinic acid catalysed hydrosilanes reduction of tertiary amides: a mild and chemoselective synthesis of amines
Chardon, A.; Mohy El Dine, T.; Legay, R.; De Paolis, M.; Rouden, J.; Blanchet, J.
Chem.-Eur. J. 2017, 23, 2005-2009.

Influence of methyl and propyl groups on the vibrational spectra of two imidazolium ionic liquids and their non-ionic precursors
Kiefer, J.; Haddad, B.; Mokhtar, D.; Goussem, M.; Belarbi, E.-H.; Villemin, D.; Bresson, B.; Rahmouni, M.
Journal of Molecular Structure 2017, 1134, 582-590.
DOI: org/10.1016/j.molstruc.2017.01.008

Synthesis of fluoropyrrolidines and (fluoroalkyl)pyrrolidines
Pfund, E.; Lequeux, T.
Synthesis 2017, 49, 3848–3862.
DOI: 10.1055/s-0036-1589078

Synthesis of 5,5-difluoro-5-phosphono-pent-2-en-1-yl nucleosides as potential antiviral agents
Chevrier, F.; Chamas, Z.; Lequeux,T.; Pfund, E.; Andrei, G.; Snoeck, R.; Roy, V.; Agrofoglio, L. A.
RSC Adv. 2017, 7, 32282–32287.
DOI: 10.1039/c7ra05153k

Fluorescent anticancer quinazolines as molecular probes for ß-tubulincolchicine site competition assay and visualization of microtubules as intracellular targeting sites
Suzuki,Y.; Sawada, J.; Hibner, P.; Ishii, H.; Matsuno,K.; Sato,M.; Witulski, B.; Asai, A.
Dyes and Pigments 2017, 145, 233-238.
DOI: 10.1016/j.dyepig.2017.05.050

1,4,9,12-Tetra­meth­­oxy-14-octyl-5,8-di­hydro­diindolo[3,2-b;2′,3′-h]carbazole with an unknown solvent
Wrobel, N.; Witulski,B.; Schollmeyer, D.; Detert, H.
Organic Compounds, 2017, 2 (art 3), x170462
DOI: 10.1107/S241431461700462X

Zinc mediated straightforward access to diacylpyrroles
Faye, D.; Mbaye, M. D.; Coufourier, S.; Lator, A.; Dieng, S. Y.; Gaillard, S.; Renaud, J. L.,
Comptes Rendus Chimie 2017, 20 (5), 492-499.
DOI: 10.1016/j.crci.2017.01.003

Mechanistic investigations of reactions of the frustrated Lewis pairs (triarylphosphines/B(C6F5)3) with Michael acceptors
Dupré, J.; Gaumont, A.-C.; Lakhdar, S.
Org. Lett. 2017, 19(3), 694-697.

Transition metal-free stereospecific access to (E)-(1-fluoro-2-arylvinyl)phosphine borane complexes
Rousée, K.; Pannecoucke,X.; Gaumont,A.-C.; Lohier,J.-F.; Morlet-Savary,F.; Lalevée, J.; Bouillon,J.-P.; Couve-Bonnaire, S.; Lakhdar, S.
Chem. Commun., 2017,53, 2048-2051
DOI: 10.1039/C6CC09673E

Synthesis of methionine-derived endocyclic sulfilimines and sulfoximines
Marzag, H.; Schuler, M.; Tatibouët, A.; Reboul, V.
Eur. J. Org. Chem. 2017, 896-900.
DOI : 10.1002/ejoc.201601515

Mechanistic investigation of the NH-sulfoximination of sulfide. Evidence for λ6-sulfanenitrile intermediates
Lohier, J.-F.; Glachet, T.; Marzag, H.; Gaumont, A.-C.; Reboul, V.
Chem. Commun. 2017, 53, 2064-7.
DOI: 10.1039/c6cc09940h

Unique reactivity of -substituted electron-deficient allenes using sulfinate salts as Lewis Base organocatalysts
Martzel, T.; Lohier, J.-F.; Gaumont, A.-C.; Brière, J.-F.; Perrio, S.
Adv. Synth. Catal. 2017, 356 (1), 96-106.
DOI: 10.1002/adsc.201600929

Effect of the micro-wave irradiations onorption of Alkylimidazolium salts on the bentonite
Elias, A.; Abdellah, Z. N.; Villemin, D.; Hazimeh, H.; Didi, M. A.
Chem. Paper. 2017, 71(1), 59-65.
DOI : 10.1007/s11696-016-0037-z

How do phosphinates react with unactivated alkenes under organic photocatalyzed conditions? Substrate scope and mechanistic insights
Fausti, G.; Morlet-Savary, F.; Lalevée, J.; Gaumont, A.-C.; Lakhdar, S.
Chem. Eur. J. 2017, 23, 1-6.
DOI: 10.1002/chem.201604683
Selected as a Hot Paper by the Editor of Chemistry a European Journal

Investigation of the effect of piperidin-1-yl-phosphonic acid on corrosion of iron in sulfuric acid
M.R.Laamari, J. Benzakour, F. Berrekhis, M. Bakasse, D. Villemin,
Arab. J. Chem, 2016, 9,  Sup. 2, S1218-S122.

Influence of methyl and propyl groups on the vibrational spectra of two imidazolium ionic liquids and their non-ionic precursors
Kiefer, J.; Haddad, B.; Mokhtar, D.; Goussem, M.; Belarbi, E.-H.; Villemin, D.; Bresson, B.; Rahmouni, M.,
Journal of Molecular Structure, 2016 under Press

Chemoinformatics and stereoisomerism: A stereo graph kernel together with three new extensions
Grenier, P.-A.; Brun, L.; Villemin, D.
Pattern recognition Letters 2016, under press
DOI: 0.1016/j.patrec.2016.06.025

Synthesis and molecular properties of methoxy-substituted diindolo[3,2-b:2,3-h]carbazoles for organic electronics obtained by a consecutive twofold Suzuki and twofold Cadogan reaction
Srour, H.; Doan, T.-H.; Da Silva, E.; Whitby, R. J.; Witulski, B.
J. Mater. Chem. C 2016, 4, 6270-6279.
DOI: 10.1039/C6TC02009G.

Nine-ring angular fused biscarbazoloanthracene displaying a solid state based excimer emission suitable for OLED application
Baryshnikov, G. V.; Gawrys, P.; Ivaniuk, K; Witulski, B.; Whitby, R. J.; Al-Muhammad, A.; Minaev, B.; Cherpak, V; Stakhira, P.; Volyniuk, D.; Wiosna-Salyga, G.; Luszczynska, B.; Lazauskas, A.; Tamuleviciush, S.; Grazulevicius, J. V.
J. Mater. Chem. C 2016, 4, 5795-5805.
DOI: 10.1039/C6TC01469K

Highly luminous sky-blue organic light-emitting diodes based on the Bis[(1,2)(5,6)]indoloanthracene emissive layer
Ivaniuk, K.; Cherpak, V.; Stakhira, P.; Hotra, Z.; Minaev, B.; Baryshnikov, G.; Stromylo, E.; Volyniuk, D.; Grazulevicius, J. V.; Lazauskas, A.; Tamulevicius, S.; Witulski, B.; Light, M. E.; Gawrys, P.; Whitby, R. J.; Wiosna-Salyga, G.; Luszczynska, B.
J. Phys. Chem. C 2016, 120, 6206-6217.
DOI: 10.1021/acs.jpcc.6b00696

Application of ynamides in the synthesis of 2-(tosylamido)- and 2,5-Bis(tosylamido)thiophenes
Talbi, I.; Alayrac, C.; Lohier, J.-F.; Touil, S.; Witulski, B.
Org. Lett. 2016, 18, 2656-2659.
DOI: 10.1021/acs.orglett.6b01101

Natural bond orbital analysis of cyclic and acyclic C-H acids
Villemin, D.; Charif, I. E.; Mekelleche, S. M.; Bar, N.
Eur. Chem. Bull. 2016, 5, 274-279.
DOI: 10.17628/ECB.2016.5.274

Prediction of predominant configuration in the enantioselective reduction of  beta-ketoacid derivates with Baker’s Yeast using neural networks
Villemin, D.; Cherqaoui, D.; Mesbah, A.
Eur. Chem. Bull. 2016, 5, 129-131.
DOI: 10.17628/ECB.2016.5.129

An efficient recyclable magnetic material for the selective removal of organic pollutants
Monteil, C.; Boivin, E.; Bar, N.; Bee, A.; Villemin, D.
Beilstein J. Nanotechnol. 2016, 7, 1447-1453.
DOI: 10.3762/bjnano.7.136

Metal-free synthesis of 6-phosphorylated phenanthridines: synthetic and mechanistic insights
Noël-Duchesneau, L.; Lagadic, E.; Morlet-Savary, F.; Lohier, J.-F.; Chataigner, I.; Breugst, M.; Lalevée, J.; Gaumont, A.-C.; Lakhdar, S.
Org. Lett. 2016, 18, 5900-5903.
DOI: 10.1021/acs.orglett.6b02983
Highlighted in Synfacts : Synthesis of 6-Phosphorylated Phenanthridines, 2017, 13, 140.

Enantioselective phase-transfer catalyzed-sulfanylation of Iisoxazolidin-5-ones: an entry to 2,2-amino acid derivatives
Cadart, T.; Berthonneau, C.; Levacher, V.; Perrio, S.; Brière, J.-F.
Chem. Eur. J. 2016, 22, 15261-15264.
DOI: 10.1002/chem.201603910

Bis-methyl imidazolium methylidene bis(trifluoromethanesulfonyl)imide, crystal structure, thermal, and dielectric studies
Haddad, B.;Taqiyeddine, M.; Villemin, D.; Lohier, J.-F.;  Belarbi, E.-h
Bull. Mater. Sci. 2016, 39, 797-801.
DOI: BOMS-D-15-00490R2

Effect of organoclays on the degradation of polyoxymethylene homopolymer during melt processing
Ditta, A.; Laurandel, H.; Breynaert, F.; Travert, A.; Le PLuart, L.,
Pol. Degrad. Stab. 2016, 131, 122-131.
DOI: 10.1016/j.polymdegradstab.2016.07.012

A straight forward synthesis of well-defined difluorophosphonylated terminated poly( caprolactone) for grafting onto iron oxide magnetic nanoparticles
Ho, H. T.; Pascual, S.; Livi, S.; Mebold, E.; Fontaine, J.; Lequeux, T.; Pham, T.-N.
J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 2453-2458.
DOI: 10.1002/pola.28147

Recent advances in iron- and cobalt-complex-catalyzed tandem/consecutive processes Iinvolving hydrogenation
Renaud, J.-L.; Gaillard, S.
Synthesis 2016, 48, 3659-3683
DOI: 10.1055/s-0035-1562791

Evaluation of the versatile character of a nanoemulsion formulation
Gué, E.; Since, M.; Ropars, S.;Herbinet, R.; Le Pluart, L.; Malzert-Fréon, A.
Int. J. Pharm. 2016, 498, 49-65.
DOI: 0.1016/j.ijpharm.2015.12.010

Stereoselective synthesis of dehydroamino acids using malonic acid half oxyester and aromatic aldehydes
Singjunla, Y.; Colombano, S.; Baudoux, J.; Rouden, J.,
Tetrahedron 2016, 72, 2369-2375.
DOI: 10.1016/j.tet.2016.03.043

Towards a universal organocatalyst for the synthesis of enantioenriched phenylalanine derivatives by enantioselective decarboxylative protonation
Pigeaux, M.; Laporte, R.; Harrowven, D. C.; Baudoux, J.; Rouden, J.,
Tetrahedron Lett. 2016, 57, 4599-4603.
DOI: 0.1016/j.tetlet.2016.09.001

Adsorption and corrosion inhibition of carbon steel in hydrochloric acid medium by hexamethylenediamine tetra(methylene phosphonic acid)
Laamari, M. R.;  Benzakour, J.; Berrekhis, F.; Derja, A.; Villemin, D.
Arabian J. Chem. 2016, 9, 245-251.
DOI: 0.1016/j.arabjc.2011.03.018

Synthesis, crystal structure, optical, electrochemical and thermal properties of the ynamide: Bis-(N-4-methylbenzenesulfonyl,N-n-butyl)-1,3-butadiyne-1,4-diamide
Doan, T.-H.; Talbi, I.; Lohier, J.-F.; Touil, S.; Alayrac, C.; Witulski, B.
J. Mol. Struct. 2016, 1116, 127-134.
DOI: 10.1016/j.molstruc.2016.03.026

Access to constrained fluoropseudopeptides via ring-closing metathesis of fluoroalkenes
Guerin, D.;  Dez, I.; Gaumont, A. C.; Pannecoucke, X., Couve-Bonnaire, S.
Org. Lett. 2016, 18, 3606-3609.
DOI: 10.1021/acs.orglett.6b01631

Access to fluoropyrrolidines by intramolecular aza-Michael addition reaction
Le Guen,, C.; Tran Do, M.-L.;  Chardon, A.; Lebargy, C.; Lohier, J.-F.; Pfund, E.; Lequeux T.
J. Org. Chem. 2016, 81, 6714-6720.

Formamide synthesis through borinic acid catalysed transamidation under mild conditions
Mohy El Dine, T.; Evans, D.; Rouden, J.; Blanchet, J.
Chem. Eur. J. 2016, 22, 5894-5898
DOI: 10.1002/chem.201600234

Designing NHC-copper(I) dipyridylamine complexes for blue light-emitting electrochemical cells
Elie, M.; Sguerra, F.; Di Meo, F.; Weber, M. D.; Marion, R.; Grimault, A.; Lohier, J.-F.; Stallivieri, A.; Brosseau, A.; Pansu, R. B.; Renaud, J.-L.; Linares M.; Hamel, M.; Costa, R. D.; Gaillard, S.
ACS Appl Mater Interfaces, 2016, 15, 14678-14691.
DOI: 10.1021/acsami.6b04647.

Metal-free, visible light-photocatalyzed synthesis of benzo[b]phosphole oxides: synthetic and mechanistic investigation
Quint, V.; Morlet-Savary, F.; Lohier, J.-F.; Lalevée, J.; Gaumont, A.-C.; Lakhdar, S.
J. Am. Chem. Soc. 2016, 138, 7436-7441.
DOI: 10.1021/jacs.6b04069
Highlighted in Synfacts, 2016, 12, 862.

Convenient access to meso benzylic bisalkynes
Bulman, P. C.; Richard, S. G.; Harvey, J.; Gaumont, A.-C.; Alayrac, C.; Slawin, A. M. Z.
Synlett, 2016, 27, 961-964.
DOI : 10.1055/s-0035-1561318

Enantiomerically pure [2.2]Paracyclophane-4-thiol: a planar chiral sulfur-based building block readily available by resolution with an amino acid chiral auxiliary
Vincent, A.; Deschamps, D.; Martzel, T.; Lohier, J.-F.; Richards, C. J.; Gaumont, A.-C.; Perrio, S.
J. Org. Chem. 2016, 81, 3961-3966.
DOI : 10.1021/acs.joc.6b00560

Photopolymerization study and adhesive properties of self-etch adhesives containing bis(acyl)phosphine oxide initiator
Besse, V.; Derbanne, M. A.; Pham, T.-N.; Cook, W. D.; Le Pluart, L.
Dental Materials 2016, 32, 561-569.

Easy solventless synthesis of new mono and bis amino-5H-chromeno [3,4-c] pyridin-5-one derivatives
Kibou, A.; Villemin, D.; Lohier, J.-F.; Cheikh, N.; Bar, N.; Choukchou-Braham, N.
Tetrahedron 2016, 72, 1653-1661.
DOI : 10.1016/j.tet.2016.01.063

Iridium-based Inhibition of Tumour Necrosis Factor-a: Influence of the Ligand and the Light
Sauvageot, E.; Lafite, P.; Duverger, E.; Marion, R.; Hamel, M.; Gaillard, S.; Renaud, J.-L.; Daniellou, R.
J. Organomet. Chem. 2016, 808, 122-127.

Achiral bifunctionnal (cyclopentadienone)iron tricarbonyl complexes embedded in streptavidin : Application in asymmetric hydrogenation
Mérel, D. S.; Gaillard, S.; Ward, T. ; Renaud, J.-L.
Catal. Lett. 2016, 146, 564-569
DOI : 10.1007/s10562-015-1681-6

Room-temperature alkynylation of phosphine oxides with copper acetylides: practical synthesis of alkynylphosphine oxides
Gerard, P.; Veillard, R.; Alayrac, C.; Gaumont A.-C.; Evano, G.
Eur. J. Org. Chem. 2016, 633-638.
DOI: 10.1002/ejoc.201501440

Neodymium (III) removal by functionalized magnetic nanoparticles
Didi, M.-A.; Miraoui, A.;  Villemin, D.; Monteil, C.
J. Rad. Nucl. Chem. 2016, 307, 963-971
DOI : 10.10007/s10967-015-4267-2

Activated zeolites and heteropolyacids have efficient catalysts for synthesis without use of organic solvent at room temperature
M. Hammadi; H. Dokari; D. Villemin; N. Benferrah
Springer International Publishing in Progress in Clean Energy, 2015, 1, 38, 535-549.
DOI: 10.1007/978-3-319-16709-1_38.

Boronic acid catalysed peptide synthesis
Mohy El Dine, T.; Rouden, J.; Blanchet, J.
Chem. Commun. 2015, 51 (89), 16084-16087.
DOI: 10.1039/C5CC06177F

Synthesis of 1,3 thiazines by a three-component reaction and their transformations into
beta-lactam-condensed 1,3-thiazine and 1,4 thiazine derivatives
Peudru, F.; Lohier, J.-F.; Gulea, M.; Reboul, V.
Phosphorus, Sulfur, and Silicon and the Related Elements
, 2015, 191, 220-229.
DOI: 10.1080/10426507.2015.1072191

Catalytic chemical amide synthesis at room temperature: one more step toward peptide synthesis

Mohy El Dine, T.; Erb, W.; Berhault, Y.; Rouden, J.; Blanchet, J.
J. Org. Chem. 2015, 80 (9), 4532-4544
DOI: 10.1021/acs.joc.5b00378

Bioinspired, base- and metal-free, mild decarboxylative aldol activation of malonic acid half thioesters under phase-transfer reaction conditions
Bew, S. P.; Stephenson, G. R.; Rouden, J.; Ashford, P.-A.; Bourane, M.; Charvet, A.; Dalstein, V. M. D.; Jauseau, R.; Hiatt-Gibson, G.D.; Martinez-Lozano, L. A.
Adv. Synth. Catal. 2015, 357 (6), 1245-1247.
DOI: 10.1002/adsc.201400915

An organocatalytic access to spiro[4.5]decanes and spiro[4.6]undecanes containing aminolactones and 3-aminopyrrolidines
Cormier, M.; Chardon, A.; Blanchet, J.; Rouden, J.; Maddaluno, J.; De Paolis, M.
Synthesis, 2015, 47(17), 2549-2553.
DOI: 10.1055/s-0034-1380146

Synthesis and characterization of innovative well- defined difluorophosphonylated-(co)polymers by RAFT polymerization
Ho, H.-T.; Coupris, J.;  Pascual, S.; Fontaine, L; Lequeux, T.; Pham, T.-N.
Polym. Chem. 2015, 6, 4597-4604.
DOI: 10.1039/C5PY00690B

Catalysis by triflic acid: Synthesis of the indolylquinones as potential antitumor agent
Dridi, F.; Villemin, D.;  Bar, N.; Hachemi, M.; Legay, R.
Eur. Chem. Bull., 2015, 4 (12), 543-547.
DOI: 10.17628/ECB.2015.4.543

Synthesis, characterization and electrical study of new bis-fused tetrathiafulvalene contains functional groups .
Boumedjout, M.; Bendjeddou, A.; Abbaz, T.;  Tiaouianine,  S.; Kaboub, L.; Gouasmia, A.;  Villemin, D.
Oriental J. Chem. 2015, 31 (4), 1887-1895

Aminomethylenephosphonic Acids Syntheses and Applications (A Review)
Villemin, D.;  Didi, M.-A.
Orient. J. Chem., 2015, 31, 1-12.
DOI:  org/10.13005/ojc/31.Special-Issue1.01

Convenient access to new 4-substituted aminopyrido[2,3-d] pyrimidines derivatives
Belhadj, F.; Kibou, Z.; Cheikh, N.; Choukchou-Braham, N.; Villemin, D.
Tetrahedron Lett., 2015, 56, 5999-6002.
DOI: 10.1016/j.tetlet.2015.09.042.

From bags of graphs to stereo subgraphs in order to predict molecule’s
Grenier, P.-A.; Luc Brun, L.; Villemin, D.
Lecture Notes in Computer Science, 2015, 9069, 305-314.

Study of imidazoliumdicationic ionic liquids by Raman and FTIR spectroscopies: the effect of the nature of the anion
Moumene, T.; Belarbi, E.H.;  Haddad, B.; Villemin, D.; Abbas, O.; Khelifa, B.; Bresson, B.
J. Mol. Struct., 2015, 1083,179-186.
DOI :10.1016/j.molstruc.2014.11.061

Phosphonated polyethyleneimines (PEIP) as multi-use polymers
Villemin, D.; Monteil, C.; Bar, N.; Didi, M.-A.
Phosphorous, Sulfur Silicone, 2015, 190, 879-890
DOI : 10.1080/10426507.2014.981633

Including chemical information to Treelet Kernel
Gaüzère, B.; Grenier, P.-A.; Brun, L.; Villemin, D.
Pattern Recognition, 2015, 48, 356-367.

Chirality Control in Planar Chiral Cobalt Oxazoline Palladacycles
Cassar, D.; Roghzai, H.; Villemin, D.; Horton, P.; Coles, S.; Richards, C.
Organometallics, 2015, 34 (12), 2953-2961.
DOI: om-2015-00282q.R1.

Asymmetric isomerization of allylic alcohols
Cahard, D.; Gaillard, S.;  Renaud, J.-L.
Tetrahedron Lett. 2015, 56, 6159-6169.

Iron-Catalyzed Carbon-Nitrogen, Carbon-Phosphorus, and Carbon-Sulfur Bond Formation and Cyclization Reactions
Renaud, J.-L.;  Gaillard, S.
Top. Organomet. Chem. 2015, 50, 83-144.
DOI: 10.1007/3418_2015_103

tert-Butyl Sulfoxides: Key Precursors for Palladium-Catalyzed Arylation of Sulfenate Salts
Gelat, F.; Lohier, J.-F.; Gaumont A.-C.; Perrio, S.
Adv. Synth. Catal., 2015, 357, 2011-2016.
DOI: 10.1002/adsc.201500368

Highly Active Phosphine Free Bifunctional Iron Complex for Hydrogenation of Bicarbonate and Reductive Amination

Thai, T-T.; Mérel, D. S.;  Poater, A.;   Gaillard, S.; Renaud, J.-L.
Chem. Eur. J. 2015, 21, 7066-7070.
DOI: 10.1002/chem.201500720

Samarium (III) removal by liquid-liquid and solid-phase extraction kinetics and thermodynamics aspects
Amara-Rekkab, A.; Didi, M. A.; Villemin, D.
Eur. Chem. Bull. 2015, 4, 190-195
DOI: 10.17628/ECB.2015.4.190

Molecular mobility and physical ageing of plasticized poly(lactide)
Dobircau, L.; Delpouve, N.; Herbinet R.; Domenek, S.. Le Pluart, L.; Ducruet, V.; Dargent, E.
Polym. Eng. Sci., 2015, 55, 858-865.
DOI: 10.1002/pen.23952

Chitosan: an Upgraded Polysaccharide Waste for Organocatalysis
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Eur. J. Org. Chem., 2015, 12, 2559-2578.

Hollow micropsheres-polypropylene blends : relationship between microsheres degradation and composites properties
Doumbia, A. -S; Bourmaud, A.; Jouannet, D.; Fahler, T.; Orange, F.; Retoux, R.; Le Pluart, L; Cauret, L.
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Synthesis of Fluorine Containing 3,3-Disubstituted Oxetanes and Alkylidene Oxetanes
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Synthesis of fluorinated and CF3 substituted alkenes through the modified Julia olefination: an update
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Synthesis of 7-((dioctylamino)methyl)quinolin-8-ol. Application in the liquid-liquid extraction
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Physical Ionic Liquid/Polysiloxane Mixtures for Tuning the Polarity and the Selectivity of the Polysiloxane Stationary Phase for GC Analysis, Chromatographia
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Biopolymer Supported Ionic Liquid Phase (bio-SILP) Ruthenium Catalyst for Olefin Metathesis
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Valorisation des déchets élastomères : du déchet pneumatique au polymère fonctionnel
Mouawia, A.; Nourry, A.;  Gaumont, A.-C.;  Pilard J.-F.;  Isabelle Dez, I. L’actualité chimique  2014 – n° 390- p.88-89

Microwave-irradiation and flow chemistry for a straightforward  synthesis of piano-stool iron complexes.
Pagnoux-Ozherelyeva, A.; Bolien, D.; Gaillard, S.; Peudru, F.; Lohier, J.-F.; Whitby, R. J.; Renaud, J.-L.
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Tuning morphology of GeS2 hybrid materials using Ionic Liquids as structuring agent
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European Journal of Inorganic Chemistry 2014, 6232-6238.

Iron-Catalyzed Hydrogenation of Esters to Alcohols
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Angew. Chem. Int. Ed. 2014, 53, 13004-13006.

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Silyl alkynylphosphine-boranes: key precursors of triazolylphosphines via tandem desilylation-Click chemistry
Veillard, R.; Bernoud, E.; Abdellah, I.; Lohier, J.-F.; Alayrac, C.; Gaumont, A.-C.
Org. Biomol. Chem. 2014, 12, 3635-3640.

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Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung
Evano, G.;  Jouvin, K.; Theunissen, C.; Guissart, C.; Laouiti, A.; Tresse, C.; Heimburger, J.; Bouhoute, Y.; Veillard, R.; Lecomte, M.; Nitelet, A.; Schweiser, S.; Blanchard, N.; Alayrac, C.; Gaumont, A.-C.
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An easy route to (hetero)arylboronic acids
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Perrio, S.
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Stereoselective formation of (Z)-2-fluoroalkenoates via Julia Kocienski reaction of aldehydes with pyrimidinyl-fluorosulfones
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Cu-modified hydroxy-Apatite as catalyst for the Glaser-Hay C-C homo- coupling reaction of terminal alkynes
Maaten, B.;  Moussa, J.; Desmarets, C.; Gredin, P.;  Beaunier, P.; Kanger, T.;   Tõnsuaadu, K.;  Villemin, D.; Gruselle, M.
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New unsymmetrically benzene-fused bis (tetrathiafulvalene): Synthesis, characterization, electrochemical properties and electrical conductivity of their materials

Abbaz, T.;   Bendjeddou, A.; Gouasmia, A.; Villemin, D.; Takashi Shirahata, T.
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Vibrational spectroscopic study of ionic liquids: comparison between monocationic and dicationic imidazolium ionic liquids
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Liquid-liquid extraction of thorium (IV) by fatty acids. A comparative study

Didi, M. A.; Villemin, D.; Abderrahim,O.; Azzouz, A.
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New dicationic piperidinium hexafluorophosphate ILs, Synthesis, characterization and dielectric measurements
Haddad, B.; Villemin, D.; Belardi, E.-h.; Bar, N.; Rahmouni, M.
Arabian Journal of Chemistry 2014, 717-787.
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Fluorophosphonylated Monomers for Dental Applications
Derbanne, M.; Zulauf, A.; LeGoff, S.; Pfund, E.; Sadoun, M.; Pham, T.-N.; Lequeux, T.
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Synthesis of fluorinated agonist of sphingosine-1-phosphate receptor 1
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Bioorganic & Medicinal Chemistry 2014, 22, 4955-4960.
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NHC Copper(I) Complexes Bearing Dipyridylamine Ligands: Synthesis, Structural and Photoluminescent studies
Marion, R.; Sguerra, F.; Di Meo, F.; Sauvageot, E.; Lohier, J.-F.; Daniellou, R.; Renaud, J.-L.; Linares, M.; Hamel, M.; Gaillard, S.
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The effect of functional monomer chain spacer length on thebond strenght of an experimental dental adhesive
Derbanne, M. A.; Besse, V.; Le Goff, S.; Sadoun, M.; Pham, T.-N.
International Journal of Adhesion and Adhesives 2014, 95-105.
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New complexone derivatives of 8-hydroxy-quinoline and theirs application in UO22+ extraction
Zaoui, F.; Villemin, D.; Bar, N.
European Chemical Bulletin 2014, 3, (8), 783-787.

Novel unsymmetrically p-acetoxyphenyl and p-hydroxyphenyl tetrathiafulvalenes: synthesis, electrochemical properties and electrical conductivity of their charge transfer complexes
Bouchouk, D.; Bendjeddou, A.; Abbaz, T.; Gouasmia, A.; Aouf, N.-E.; Villemin, D.
Indian Journal of Chemistry Section B 2014, 53, (7), 884-889.

Iridium(III) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions
Sauvageot, E.; Marion, R.; Sguerra, F.; Daniellou, R.; Hamel, M.; Gaillard, S.; Renaud, J.-L.
Organic Chemistry
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Factorial design in optimization of extraction procedure for copper using Aliquat 336/TBP based supported liquid membrane
Medjahed, B.;  Didi, M. A.; Villemin, D.
Desalin. Water Trait., 2014, 52, (12-16), 3237-3245.
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Zinc and cobalt complexes based on tripodal ligands: synthesis, structure and reactivity toward lactide.
Tschan, M. J-L; Guo, J.; Raman, S.- K.; Brulé, E.; Roisnel, T.; Rager, M.-N.; Legay, R.; Durieux, G.; Rigaud, B.; Thomas, C. M.
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A copper-catalyzed variant of the Michaelis-Arbuzov reaction
Ballester, J.; Gatignol, J.; Schmidt, G.; Alayrac, C.; Gaumont, A.-C.; Taillefer, M.
ChemCatChem, 2014, 6, 1549-1552.
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Access to fluorinated lactams through ring-closing metathesis of reluctant fluoroalkenes promoted by appropriate substitution of a double bond
Guerin, D.; Gaumont, A.-C.; Dez, I.; Mauduit, M.; Couve-Bonnaire, S.; Pannecoucke, X.
ACS Catal., 2014, 4, 2374-2378.
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Reduction of S=O and SO2 to S, S-X to S-H, and P=O to P.
Gaumont, A.-C.; Gulea, M.; Perrio, S.;  Reboul, V.
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Supercritical CO2-ionic liquids: green combination for preparing foams
Livi, S.; Pham, T.-N.; Gerard, J.-F.; Duchet-Rumeau, J.
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Synthesis of palladium-bidentate complex and its application in Sonogashira and Suzuki coupling reactions.
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Phosphonated polyethylenimine coated nanoparticles: elaboration of size and zeta potential adjustable nanomaterials

Monteil, C.; Bar N.; Moreau, B.; Retoux, R.;  Bee, A.; Talbot, D.;  Villemin, D.
Part. Part. Syst. Char. 2014, 31 (2), 219-227.
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(-)-Cytisine and Derivatives: Synthesis, Reactivity and Applications
Rouden, J.; Lasne, M.-C. ; Blanchet, J.; Baudoux, J.
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Metal-catalyzed synthesis of hetero-substituted alkenes and alkynes
Evano, G.; Gaumont, A.-C.; Alayrac, C.; Wrona, E. I.; Giguere, J. R.; Delacroix, O.; Bayle, A.; Jouvin, K.; Gatignol, J.; Silvanus, A. J.
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Synthesis of substituted exo-glucals via a modified Julia olefination and identification as selective -glucosidase inhibitors
Habib S.; Larnaud F.; Pfund E.; Mena Barragán T.; Lequeux T.; Ortiz Mellet C.; Goekjian P. G.; Gueyrard D.
Org. Biomol. Chem. 2014, 690-699.
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Iron(II)-catalysed[2+2+2] cycloaddition for pyridine ring construction
Richard, V.; Ipouck, M.; Merel, D. S.; Gaillard, S.; Whitby, R. J.; Wiltulski, B.; Renaud, J.-L.
Chemical Communications, 2014, 50, 593-595.
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Partially phosphonated polyethylenimine-coated nanoparticles as convenient support for enzyme immobilization in bioprocessing
Monteil,C.;  Bar, N.; Retoux,R.; Henry, J.; Bernay, B.; Villemin, D.
Sensors and Actuators B, 2014, 192, 269-274.
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Iron (II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones
Cahard, D.; Bizet, V.; Dai, X.; Gaillard, S.; Renaud, J.-L.
J. Fluor. Chem. 2013, 155, 78-82.
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Straightforward synthesis of substituted dibenzyl derivatives
Mboyi, C. D.; Gaillard, S.; Mbaye, M. D.; Pannetier, N.; Renaud, J.-L. Tetrahedron 2013, 69, 4875-4882.
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Sorption efficiency of a new sorbent towards cadmium(II) : methylphosphonic acid grafted polystyrene resin

Nacer, F.; Omar, A.; Didi, M. A.; Villemin, D.
J. Chem. 2013, Article ID 980825, 10 pages.
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Asymmetric three-component domino reaction: an original access to chiral nonracemic 1,3-thiazin-2-ones
Peudru, F.; Le Cavelier, F.; Lohier, J.-F.; Gulea, M.; Reboul, V.
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Bifunctional (cyclopentadienone)iron tricarbonyl complexes: synthesis, computational studies and application in reductive amination

Moulin, S.; Dentel, H.; Pagnoux-Ozherlyeva, A.; Gaillard, S.; Poater, A.; Cavallo, L.; Lohier, J.-F.; Renaud, J.-L.
Chem Eur. J. 2013
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An investigation of the asymmetric Huisgen « Click » reaction

Buttress, J. P.; Deschamps, D.; Lancelot, M.; Martin, J.-P.; Sheldon, A. I. G.; Alayrac, C.; Gaumont, A.-C.; Page, P. C. B.; Stephenson, G. R.
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Chiral Non Racemic Sulfoxides by Asymmetric Alkylation of Alkanesulfenates in the Presence of a Chiral Ammonium Phase Transfer Catalyst Derived from Cinchona Alkaloid

Gelat, F.; Gaumont, A.-C.; Perrio, S.
J. Sulfur Chem. 2013, 34, 596-605.
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Ruthenium-catalyzed one pot tandem isomerization-transfert hydrogenation reactions of g-CF3 allylic alcohols and beta-CF3 enones
Bizet, V.; Pannecoucke, X.; Renaud, J.-L.; Cahard, D.
Adv. Synth. Catal. 2013, 355, (7), 1394-1402.
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Synthesis of -CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed redox isomerization
Bizet, V.; Pannecoucke, X.; Renaud, J.-L.; Cahard, D.
J. Fluor. Chem. 2013, 152, 56-61.
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Bifunctional iron complexes: efficient catalysts for C=O and C=N reduction in water
Merel, D. S.; Elie, M.; Lohier, J.-F.; Gaillard, S.; Renaud, J.-L.,
Chem. Cat. Chem. 2013, 5, 2939-2945.
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Direct synthesis of -hydroxy–amino-acids via diastereoselective decarboxylative aldol reaction

Singjunla, Y.; Baudoux, J.; Rouden, J.
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Hydrolytically stable acidic monomers used in two steps self-etch adhesives
Derbanne, M. A.; Besse, V.; LeGoff, S.; M. Sadoun; Pham, T.-N.
Polymer Degradation and Stability 2013, 98, 1688-1698.
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Polymerization kinetics of phosphonic acids and esters using an iodonium Initiator
Besse,V.;  Le Pluart, L.; Cook, W. D.;  Pham, T.-N.;  Madec, P-J.
J. Polym. Sci. Pol. Chem., 2013, 51 (23), 5046-5055.
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Iron-salt-promoted highly regioselective alpha and beta hydrophosphination of alkenyl arenes
Routaboul, L.; Toulgoat, F.; Gatignol, J.; Lohier, J.-F.; Norah, B.; Delacroix, O.; Alayrac, C.; Taillefer,M.; Gaumont A.-C.
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Unprecedented synthesis of alkynyl phosphine-boranes through room-temperature oxidative alkynylation
Jouvin, K.; Veillard, R.; Theunissen, C.; Alayrac, C.; Gaumont, A.-C.; Evano, G.
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Investigation of 7-((dioctylamino)methyl)quinoline-8-ol for uptake and removal of uranyl ions.
Zaoui, F.; Didi, M. A.; Villemin, D.
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Preparation, characterization and thermal stability of bentonite modified whith bis-imidazolium salts

Makhoukhi, B.; Didi, M. A.; Villemin, D.
Mat. Chem. Phys., 2013, 138, 199-203.
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Comparative study of uranium (VI) extraction between Lewatit TP 260, polyethyleniminephenylphosphonamidic acid & diaminotriphosphonic acid grafted polystyrene divinyl benzene resins
Kadous, A.;  Abderrahim,O.;  Didi, M. A.;  Villemin,D.
Inter. J. Eng. Res. Apl. (IJERA), 2013, 3 (1), 431-436.
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Noyau de treelets appliqué aux graphes étiquetés
Gaüzère,B.; Brun, L.; Villemin, D.
Rev. Intell. Artif. (RIA), 2013, 1, 121-144
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Antimicrobial activities of the Henna extract and some synthetic naphthoquinones derivatives
Rahmoun, N. M.; Boucherit-Atmani, Z.; Benabdallah, M.; Boucherit, K.; Villemin, D.;  Choukchou-Braham, N.
Am. J. of Med. and Biol. Res., 20131 (1),  16-22.
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Structural variability in multifunctional metal xylenediaminetetraphosphonate hybrids
Colodrero, R.; Angeli, G.; Bazaga-Garcia, M.; Olivera-Pastor, P.; Villemin, D.; Losilla, E.; Martos, E.; Hix, G.; Aranda, M.; Demadis, K.; Cabeza,  A.
Inorg. Chem., 2013, 52 (15) 8770-8783.
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Synthesis, characterization and electrochemical properties of new series of  TTF derivatives as useful components for conducting materials
Abbaz, T.; Bendjeddou, A.; Gouasmia, A. K.;  Villemin, D.
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Highly porous catalytic materials with Pd and ionic liquid supported on chitosan
Jouannin, C.; Vincent, C.;  Dez, I.;  Gaumont, A.-C.; Vincent, T.; Guibal, E.
Journal of Applied Polymer Science, 2013, 128(5), 3122-3130
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Ligand exchange reaction on Au38(SR)24, separation of Au38(SR)23(SR’)1 regioisomers and migration of thiolates
Beqa, L.; Deschamps, D.; Perrio, S.;  Gaumont, A.-C.; Knoppe, S. ; Bürgi, T.
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Copper-catalyzed synthesis of 1,3-butadienylphosphine oxides and chemoselective phosphoryl reduction to stereodefined 1,3-butadienylphosphines
Gatignol, J.; Alayrac, C.; Lohier, J.-F.; Ballester, J.; Taillefer, M.; Gaumont, A.-C.
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Role of cationisation and multimers formation for diastereomers differentiation by Ion Mobility – Mass Spectrometry

Domalain, V.; Tognetti, V.;  Hubert-Roux, M. ; Lange, C. M.; Joubert, L.; Baudoux, J.; Rouden, J.; Afonso, C.
J. Am. Soc. Mass Spectrom. 2013, 24, 1437-1445.
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An organocatalytic route to 2-heteroarylmethylene decorated N-arylpyrroles
Jean, A.; Blanchet, J.; Rouden, J.; Maddaluno, J.; De Paolis, M.
Beilstein J. Org. Chem. 2013, 9, 1480-1486.
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Malonic Acid Half Oxyesters and Thioesters: Solvent-Free Synthesis and DFT Analysis of Their Enols
Bew, S.; Stephenson, G. R.; Rouden, J.; Martinez-Lozano, L.; Seylani, H.
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Aza-Michael access to fluoroalkylidene analogues of biomolecules
Prunier, A.; Calata, C.; Legros, J.; Maddaluno, J.; Pfund, E.; Lequeux, T.
J. Org. Chem. 2013, 78, 8083-8097.
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A serendipitous conversion of enaminolactone nitriles with primary amines: a new synthesis of substituted 2-aminopyridine derivatives
Cheikh, N.; Villemin, D.; Bar, N.; Lohier, J. F.; Choukchou-Braham, N.; Mostefa-Kara, B.; Sopkova, J.
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Solventless convenient synthesis of new cyano-2-aminopyridine from enaminonitriles
Villemin, D.; Belhadj, Z.; Cheikh, N.; Choukchou-Nraham, N.; Bar, N.; Lohier, J.-F.
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Radical conjugate addition of ambiphilic fluorinated free radicals
De Schutter, C.; Pfund, E.; Lequeux, T.
Tetrahedron, 2013, 69, 5920-5926.
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Ready synthetic access to enantiopure (F) branched fluoroalkenes
Larnaud, F.; Malassis, J.; Pfund, E.; Linclau, B.; Lequeux, T.
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Stereoselective access to heteroarylmethylene-substituted pyrrolidines: fully organocatalytic Mannich-hydroamination reaction
Jean, A.; Blanchet, J.; Rouden, J.; Maddaluno, J.; Paolis, M. D.
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When phosphorus and NHC (N-heretocyclic carbene) meet each other
Gaillard, S.; Renaud, J. L.
Dalton Transactions 2013, 42, 7255-7270.
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Synthesis of fluorinated exo-glycals through modified Julia olefination

Habib, S.; Larnaud, F.; Pfund, E.; Lequeux, T.; Fenet, B.; Goekjean, P.; Gueyrand, D.

Eur. J. Org. Chem.
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Synthesis and polymerization kinetics of acrylamide phopshonic acids and esters as new dentine adhesives

Besse, V.; LePluart, L.; Cook, W. D.; Pham, T.-N.; Madec, P.-J. 
J. Polym. Sci. Part A: Polym. Chem.
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Hybrid macroporous Pd catalytic discs for 4- nitroaniline hudrogenation: contribution of the alginate-tetraalkylphosphonium ionic liquid support

Vincent, T.; Krys, P.; Jouannin, C.; Gaumont, A.-C.; Dez, I.; Guibal, E.
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Structure and rheology of polyethylene/imidazolium-based montmorillonite nanocomposites
Mederic, P.; LePluart, L.; Aubry, T.; Madec, P.-J.
J. Appl. Pol. Sci. 2013, 51, 149-157.
DOI : 10.1002/APP.37812

Isomérisation rédox: une réaction économe en atome à fort potentiel d’innovation
Bizet, V.; Cahard, D.; Gaillard, S.; Renaud, J.-L.
Technique de l’ingénieur 2013, IN159.
HAL : hal-01015807

Synthetic methodologies for the preparation of b-aminothiols
Mercey, G.; Reboul, V.; Gulea, M.; Levillain, J.; Gaumont, A.-C.
Eur. J. Org. Chem. 2012, 5423-5434.

Synthesis and evaluation of new phosphonic, bisphosphonic and difluoromethylphosphonic acid monomers for dental application

Catel, Y.; Besse, V.; Zulauf, A.; Marchat, D.; Pfund, E.; Pham, T.-N.; Bernache-Assolant, D.; Degrange, M.; Lequeux, T.; Madec, P.-J.; Le Pluart, L.
European J. of Polymer 2012, 48, (2), 318-330.


Solvent free condensation of methyl pyridinium and quinolinium salts with aldehydes catalysed by DBU

Seiad, L. L.; Villemin, D.; Bar, N.; Hachemi, M.
Synth. Commun.  2012, 42, (5), 650-657.

Decarboxylation of fluorosulfones for the preparation fluoroalkylidene precursors
Larnaud, F.; Pfund, E.; Linclau, B.; Lequeux, T.
J. Fluor. Chem. 2012, 134, 128-135.

5,6-Dihydro-2H-pyranones and 5,6-dihydro-2H-pyridones and their derivatives modulate in vitro human T lymphocyte function
Baba-Hamed, Y.; Medjdoub, A.; Mostefa-Kara, B.; Merzouk, H.; Villemin, D.; Narce, M.
Mol. Cell. Biochem. 2012, 360, (1-2), 22-33.

Synthesis of a [2.2] paracyclophane based planar chiral palladacycle by a highly selective kinetic resolution/C-H activation reaction
Dendele, N.; Bisaro, F.; Gaumont, A.-C.; Perrio, S.; Richards, C. J.
Chem. Commun. 2012, 48, 1991-1993.

Asymmetric diastereoselective thia-hetero-Diels-Alder reactions of dithioesters
Dentel, H.; Chataigner, I.; Lohier, J.-F.; Gulea, M.
Tetrahedron 2012, 68, 2326-2335.
DOI: 10.1016/j.tet.2012.01.039
HAL: hal-01016502

Fluorophosphonylated nucleoside derivatives as new series of thymidine phosphorylase multisubstrate inhibitors
Diab, S. A.; Schutter, C. D.; Muzard, M.; Plantier-Royon, R.; Pfund, E.; Lequeux, T.
J. Med. Chem. 2012, 55, (6), 2758-2768.

Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in Csp-P bond formation
Abdellah, I.; Bernoud, E.; Lohier, J.-F.; Alayrac, C.; Toupet, L.; Lepetit, C.; Gaumont, A.-C.
Chem. Commun. 2012, 48, (34), 4088-4090.

Ruthenium catalyzed redox isomerization of trifluoromethylated allylic alcohols: mechanistic evidence for an enantiospecific pathway
Bizet, V.; Pannecouke, X.; Renaud, J. L.; Cahard, D.
Angew. Chem. Int. Ed. 2012, 51, (26), 6467-6470.
DOI: 10.1002/anie.201200827

Knölker’s iron complex: an efficient in situ generated catalyst in reductive amination of alkyl aldehydes and amines

Pagnoux-Ozherelyeva, A.; Pannetier, N.; Mbaye, M. D.; Gaillard, S.; Renaud, J.-L.
Angew. Chem. Int. Ed. 2012, 51, 4976-4980.
DOI: 10.1002/anie.201201360

Investigation of the effect of piperidin-1-yl-phosphonic acid on corrosion of iron in sulfuric acid
Laamari, M. R.; Benzakour, J.; Berrekkhis, F.; Bakasse, M.; Villemin, D.
Arabian Journal of chemistry 2012 (sous presse).

On-Column solvent-free oxidative cleavage reactions of vicinal diols by silica gel and paraperiodic acid: application to in-situ sequential oxidation and Knoevenagel reactions
Dakdouki, S. C.; Villemin, D.; Bar, N.
Eur. J. Org. Chem. 2012, (4), 780-784.
Two new graphs kernels in chemoinformatics
Gauzere, B.; Brun, L.; Villemin, D.
Pattern Recognition Letters 2012, 33, (15), 2038-2047.

Adsorption and kinetic studies of piperidin-1-yl-phosphonic acid as a corrosion inhibitor of iron in sulphuric acid medium
Laamari, M. R.; Benzakour, J.; Berrekhis, F.; Bakasse, M.; Villemin, D.
 J. Mater. Environ. Sci 2012, 3, (3), 485-496.

Synthesis, differential scanning calorimetry (DSC) and dieelectric relaxation spectroscopy (DRS) studies of N-methylpiperidinium bis(trifluoromethylsulfonyl)imide
Haddad, B.; Villemin, S.; Delarbi, E.
J. Mater. Environ. Sci. 2012, 3, (2), 312-319.

Regioselective, stereoselective, and conformationally controlled synthesis of (n4-tetraarylcyclobutadiene)(n5-carbomethoxycyclopentadienyl)cobalt metallocenes

Cassar, D. J.; Nagaradja, E.; Butler, D. C. D.; Villemin, D.; Richards, C. J.
Org. Lett. 2012, 14, (3), 894-897.

Study of alginate-supported ionic liquid and Pd catalysts
Jouannin, C.; Vincent, C.; Dez, I.; Gaumont, A.-C.; Vincent, T.; Guibal, E.
Nanomaterials 2012, 2, (1), 31-53.

Nitrophenol hydrogenation using Pd immobilized on ionic liquid-alginate spherical resins
Czulak, J.; Jouannin, C.; Vincent, T.; Dez, I.; Gaumont, A.-C.; Guibal, E.
Separation Science and Technology  2012, 47, (14-15), 2166-2176.

Metal or ammonium alginates as Lewis base catalysts for the 1,2-addition of silyl nucleophiles to carbonyl compounds
Verrier, C.; Oudeyer, S.; Dez, I.; Levacher, V.
Tetrahedron Lett. 2012, 53, 1958-1960.

Enantioselective synthesis of bio-relevant 3,5-diaryl pyrazolines
Mahé, O.; Dez, I.; Levacher, V.; Brière, J.-F.
Org. Biomol. Chem.
2012, 10, (19), 3946-3954.

Influence of the structure of the onium iodide salts on the properties of modified montmorillonite
Livi, S.; Dufour, C.; Gaumont, A.-C.; Levillain, J.; Pham, T.-N.
J. of Applied Polymer Science 2012, 127 (5), 4015-4016.

Uranium micelle-mediated extraction in acetate medium: factorial design optimization
Sanaa, N.-T.; Didi, M. A.; Villemin, D.,
J. Radioanal. Nucl. Chem 2012, 293, 789-795.

Straightforward synthesis of monofluoroalkenes
Larnaud, F.; Lequeux, T.
Chimica Oggi/Chemistry Today 2012, 30, 4-6.

Copper(II) n-alkylphosphonates used as nanofilters: single crystal, powder structure studies and influence of the alkyl chain length on the magnetic properties
Chausson, S.; Rueff, J. M.; Lepetit, M. B.; Perez, O.; Retoux, R.; Simon, C.; LePluart, L.; Jaffres, P. A.
European J of Inorg. Chem. 2012, (13), 2193-2202.

Synthesis of a new chiral sulfonic acid
Das, J.; Cavelier, F. L.; Rouden, J.; Blanchet, J.
Synthesis 2012, 44, (9), 1349-1352.

High proton conductivity in a flexible, cross-linked, ultramicroporous magnesium tetraphosphonate hybrid framework
Rodriguez, R. M. P.; Olivera-Pastor, P.; Losilla, E. R.; Hernandez-Alonso, D.; Aranda, M. A. G.; Leon-Reina, L.; Rius, J.; Demadis, K. D.; Moreau, B.; Villemin, D.; Palomino, M.; Rey, F.; Cabeza, A.
Inorg. Chem. 2012, 51, (14), 7689-7698.

Reply to the comment on « Cloud-point extraction of bismuth(III)with non ionic
Didi, M. A.; Sekkal, A. R.; Villemin, D.
Colloids and Surfaces A: Physicochemical and Engineering aspects 2012, 405, 90-91.

Synthesis and electrochemical properties of novel unsymmetrical bis-tetrathiafulvenes and electrical conductivity of their charge transfert complexes with tetracyanoquinodimethane (TCNQ)
Abbaz, T.; Bendjeddou, A.; Gouasmia, A.; Regainia, Z.; Villemin, D.
Int. J. of Mol. Sci. 2012, 13, (7), 7872-7885.

Two versatile route towards Cerpegin and analogues: applications of a one pot reaction to new analogues of Cerpegin
Villemin, D.; Cheikh, N.; Liao, L.; Bar, N.; Lohier, J. F.; Sopkova, J.; Choukchou-Braham, N.; Mostefa-Kara, B.
Tetrahedron 2012, 68, (24), 4906-4918.

Antibacterial and antifungal activity of lawsone and novel naphtoquinone derivatives
Rahmoun, N. M.; Boucherit-Otmani, Z.; Boucherit, K.; Benabdallah, M.; Villemin, D.
Medecine et maladies infectieuses 2012, 42, (6), 270-275.

New approaches to niotrogen containing heterocycles: enantiosemlective organocatalyzed synthesis of dihydropyridines (DHP’s), quinolizidine derivatives and dihydropyrimidines (DHPM’s)

Pham, H. T.; Chataigner, I.; Renaud, J. L.
Curr. Org. Chem. 2012, 16, (15), 1754-1775.
DOI: 10.2174/138527212802651322
HAL: hal-01016516

A new series of seven-membered cyclic sulfamides containing thiophene or pyridine units
Abbaz, T.; Bendjeddou, A.; Gouasmania, A.; Regaina, Z.; Villemin, D.
Der Chem. Sinica 2012, 3, (3), 717-721.

Aminododecyldiphosphonic acid for solvent extraction of bismuth ions
Didi, M. A.; Kaid, M. h.; GBaghdad, M.; Villemin, D.
Inter. J. Nonferrous Metal. 2012, 1, (3), 59-64.

Stoichiometric and Catalytic Synthesis of Alkynylphosphines
Bernoud, E.; Veillard, R.; Alayrac, C.; Gaumont, A.-C.
Molecules 2012, 17, 14573-14587.

Sorption efficiency of a new sorbent towards uranyl: phosphonic acid grafted Merrifield resin
Ferrah, N.; Abderrahim, O.; Didi, M. A.; Villemin, D.
 J. Radioanal. Nucl. Chem 2011, 289, (3), 721-730.

Synthesis and evaluation of a broad range of new chiral phosphine-carbene ligands for asymmetric hydrogenation
Passays, J.; Ayad, T.; Ratovelomanana-Vidal, V.; Gaumont, A.-C.; Jubault, P.; Leclerc, E.
Tetrahedron Asymmetry 2011, 22, (5), 562-574.

Preparation and flame retardancy properties of novel PA12 and PE layered titanoniobates nanocomposites
Chausson, S.; Retoux, R.; Rueff, J. M.; Le PLuart, L.; Lequeux, T.; Madec, P.-J.; Gamino, G.
Macromol Symp 2011, 301, (1), 40-45.

De Pasteur aux liquides ioniques chiraux. Petite histoire de l’induction asymetrique promue par le solvant
Gaumont, A.-C.; Genisson, Y.; Guillen, F.; Plaquevent, J.-C.
Actualité Chimique 2011, 348-349, 84-89.
HAL: hal-01016584

Hetero-Diels-Alder reactions of new sulfonylsulfines generated from -substituted methylsulfones
Dentel, H.; Lohier, J.-F.; Gulea, M.
2011, vi, 62-73.

Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds
Bernoud, E.; Alayrac, C.; Delacroix, O.; Gaumont, A.-C.
Chem. Commun. 2011, 47, 3239-3241.

Mechanistic insights into the Palladium-catalysed asymmetric phosphination of cyclo-hexenyltriflate
Julienne, D.; Delacroix, O.; Lohier, J.-F.; Oliveira-Santos, J. S. d.; Gaumont, A.-C.
Eur. J. Inorg. Chem. 2011, 2011, (16), 2489-2498.

Cyclic sulfenamide: versatile template for the synthesis of 1,4-benzothiazepines
Spitz, C.; Reboul, V.; Metzner, P.
Tetrahedron Lett. 2011, 52, 6321-6324.

Cloud-point extraction of bismuth (III) with nonionic surfactant in aqueous solutions
Didi, M. A.; Sekkal, A. R.; Villemin, D.
Colloids and Surfaces A: Physicochemical and Engineering aspects 2011, 375, (1-3), 169-177.

Removal of copper ions from aqueous solutions by a new sorbent: polyethyleneiminemethylene phosphonic acid
Ferrah, N.; Abderrahim, O.; Didi, M. A.; Villemin, D.
Desalination 2011, 269, (1-3), 17-24.

Ph2P(BH3)Li: from ditopicity to dual reactivity
Consiglio, G. B.; Queval, P.; Harrison-Marchand, A.; Mordini, A.; Lohier, J.-F.; Delacroix, O.; Gaumont, A.-C.; erard, H. G.; Maddaluno, J.; Oulyadi, H.
J. Am. Chem. Soc. 2011, 133, (16), 6472-6480.

Convergent synthesis of functionalized uoroallylamines by the Julia Kocienski reaction
Calata, C.; Pfund, E.; Lequeux, T.
Tetrahedron 2011, 67, 1398-1405.

Palladium supported on alginate/ionic liquid highly porous monoliths: application to 4-nitroaniline hydrogenation
Jouannin, C.; Dez, I.; Gaumont, A.-C.; Taulemesse, J.-M.; Vincent, T.; Guibal, E.
Applied Catalysis B: Environmental 2011, 103, (3-4), 444-452.

Thermo sensitive behavior of cellulose derivatives in dilute aqueous solutions: From macroscopic to mesoscopic scale
Fettaka, M.; Issaadi, R.; N.Moulai-Mostefa; Dez, I.; Cerf, D. L.; Picton, L.
J. Colloid Interf. Sci. 2011, 357, (2), 372-378.

Synthesis Q1 of beta- and gamma-carbolines via ruthenium and rhodium catalysed [2+2+2] cycloadditions of yne-ynamides with methylcyanoformate
Nissen, F.; Richard, V.; Alayrac, C.; Witulski, B.
Chem. Commun. 2011, 47, 6656-6658.

Metal Free SN2′ Decarboxylative Rearrangement of beta-Ketoesters
Bizet, V.; Lefebvre, V.; Baudoux, J.; Lasne, M.-C.; Boulange, A.; Leleu, S.; Franck, F.; Rouden, J.
Eur. J. Org. Chem. 2011, (22), 4170-4175.
DOI: 10.1002/ejoc.201100120
HAL: hal-01017341

Removal of Uranium (VI) from acetate medium using Lewatit TP 260 resin
Kadous, A.; Didi, M. A.; Villemin, D.
J. Radioanal. Nucl. Chem 2011, 288, 553-561.

Efficient synthesis of new butenolides by subsequent reactions: application for the synthesis of original iminolactones, bis-iminolactones and bis-lactones

Cheikh, N.; Bar, N.; Choukchou-Braham, N.; Mostefa-Kara, B.; Lohier, J.-F.; Sopkova, J.; Villemin, D.
Tetrahedron 2011, 67, (8), 1540-1551.

Corrosion inhibition of carbon steel in hydrochloric acid 0.5 M by hexamethylene diaminetetramethyl-phosphonic acid

Laamari, R.; Benzakour, J.; Berrekhis, F.; Abouelfida, A.; Derja, A.; Villemin, D.
Arabian Journal of Chemistry 2011, 4, (3), 271-277.

New dicationic piperidinium hexafluorophosphate ILs, Synthesis, characterization and dielectric measurements
Haddad, B.; Villemin, D.; Belardi, E.-h.; Bar, N.; Rahmouni, M.
Arabian Journal of Chemistry 2011 (sous presse).
DOI: 10.1016/j.arabjc.2011.01.002

An original on-column oxidative cleavage of vicinal diols using alumina/potassium periodate: application to sequential oxidation/Horner Emmons reactions

Dakdouki, S. C.; Villemin, D.; Bar, N.
Eur. J. Org. Chem. 2011, (23), 448-4454.
DOI: 10.1002/ejoc.201100396

Adsorption and corrosion inhibition of carbon steel in hydrochloric acid medium by hexamethylenediamine tetra(methylene phosphonic acid)

Laamari, M. R.; Benzakour, J.; Berrekhis, F.; Derja, A.; Villemin, D.
Arabian Journal of Chemistry  2011(sous presse).
DOI: 10.1016/j.arabjc.2011.03.018

Organocatalytic asymmetric synthesis of sulfoxides from sulfenic acid anions mediated by a Cinchona-derived phase transfer reagent
Gelat, F.; Jayashankaran, J.; Lohier, J.-F.; Gaumont, A.-C.; Perrio, S.
Org. Lett. 2011, 13, 3170-3173.

Synthesis of difluoromethylphosphonamidates by direct addition of amine
Aliouane, L.; Rigaud, B.; Pfund, E.; Jean, L.; Renard, P.-Y.; Lequeux, T.
Tetrahedron Lett. 2011, 52, 3681-3685.
DOI: 10.1016/j.tetlet.2011.05.034
HAL: hal-01017309

Catalytic materials based on catalysts containing ionic liquid phase supported on chitosan or alginate: importance of the support
Clousier, N.; Moucel, R.; Naik, P.; Madec, P.-J.; Gaumont, A.-C.; Dez, I.
Comptes Rendus Chimie 2011, 14, (7-8), 680-684.

A new route for the synthesis of 2-aminopyridines
Kibou, Z.; Cheikh, N.; Choukchou-Braham, N.; Mostefa-Kara, B.; Villemin, D.
Scientific Study and Research-Chemistry and Chemical Engineering, Biotechnology, Food Industrie 2011, 12, (2), 121-126.

Expanding the scope of the direct regiospecific asymmetric aldol reaction to enones and dienones catalysed by a binol-derived Bronsted acid
Das, J.; Cavelier, F. L.; Rouden, J.; Blanchet, J.
Eur. J. Org Chem. 2011, 6628-6631.

[2+2+2] Cycloadditions of alkynylynamides-A total synthesis of perlolyrine and the first total synthesis of isoperlolyrine
Dassonneville, B.; Witulski, B.; Detert, H.
European J of Organic  Chemistry 2011, (15), 2836-2844.

A new sorbent for europium nitrate extraction: phosphonic acid grafted on polystyrene resin
Abderrahim, O.; Ferrah, N.; Didi, M. A.; Villemin, D.
Journal of radioanalytical and nuclear chemistry 2011, 290, (2), 267-275.

Synthesis and physical properties of new surfactants based on ionic liquids:improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites
Livi, S.; Duchet-Rumeau, J.; Pham, T.-N.; Gérard, J. F.
Journal of colloid and interface science 2011, 354, (2), 555-562.

Poly(aminome hylenephosphonic)acid for solvent extraction of metal ions
Kaid,M.; Didi, M. A.; Villemin, D.t
Scientific Study and Research-Chemistry and Chemical Engineering, Biotechnology, Food Industrie 2011, 12, (3), 269-280.

A simple and efficient procedure for a 2-pyridones synthesis under solvent-free conditions
Kibou, Z.; Cheikh, N.; Villemin, D.; Choukchou-Braham, N.; Mostefa-Kara, B.; Benabdallah, M.
Inter. J. Org. Chem. 2011, 1, 242-249.

Classification structure-activity relationship study of reverse transcriptase inhibitors
Sevagh, M.; Mazouz, E. M.; Schlitzer, A.; Villemin, D.; Jarid, A.; Cherqaoui, D.
Lett. Drug Design Disco. 2011, 8, (7), 585-595.

Crystal structures and ultramicroporosity in Mg and Ca tetraphosphonate hybrids
Colodredo, R. M. P.; Diaz, A. C.; Rius, J.; Olivera-Pastor, P.; Demadis, K. D.; Villemin, D.; Aranda, M. A. G.
Acta Cryst. (A) 2011, A67, C710-711.

In-bulk formation of a new tetrasubstituted furan from phenolic antioxidants and dibasic lead stéarate
Leconte, S.; Cena, A.; Balquet, A.; Cauret, L.; Fahler,T.; Jouannet, D.; Dhal, R.; Montembault, V.; Madec, P.-J.; Gondard, C.
Polymer Degrad. Stabil. 2015, 114, 146-153.
DOI: 10.1016/j.polymdegradstab.2010.10.014


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